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Lipos that recharge in 10 seconds

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Ted Campanelli - 12 Mar 2009 01:30 GMT
This is still in the works, but they say in 2 - 3 years we will be able
to get them.

http://tech.yahoo.com/news/nm/20090311/tc_nm/us_batteries_3

U.S. engineers find way to build a better battery (Reuters)

    * Posted on Wed Mar 11, 2009 7:15PM EDT

CHICAGO (Reuters) - U.S. engineers have found a way to make lithium
batteries that are smaller, lighter, longer lasting and capable of
recharging in seconds.

The researchers believe the quick-charging batteries could open up new
applications, including better batteries for electric cars.

And because they use older materials in a new way, the batteries could
be available for sale in two to three years, a team from Massachusetts
Institute of Technology reported on Wednesday in the journal Nature.

Current rechargeable lithium batteries can store large amounts of
energy, making them long-running. But they are stingy about releasing
their power, making them discharge energy slowly and require hours to
recharge.

Scientists traditionally have blamed slow-moving lithium ions -- which
carry charge across the battery -- for this sluggishness.

However, about five years ago, Gerbrand Ceder and a team at MIT
discovered that lithium ions in traditional lithium iron phosphate
battery material actually move quite quickly.

"It turned out there were other limitations," Ceder said in a telephone
interview.

Ceder and colleagues discovered that lithium ions travel through tunnels
accessed from the surface of the material. If a lithium ion at the
surface is directly in front of a tunnel entrance, it can quickly
deliver a charge. But if the ion is not at the entrance, it cannot
easily move there, making it less efficient at delivering a charge.

Ceder and colleagues remedied this by revamping the battery recipe. "We
changed the composition of the base material and we changed the way it
is made -- the heat treatment," Ceder said.

This created many smooth tunnels in the material that allow the ions to
slip in and out easily. "The trick was knowing what to change," he said.

Using their new processing technique, the team made a small battery that
could be fully charged in 10 to 20 seconds.

Ceder thinks the material could lead to smaller, lighter batteries
because less material is needed for the same result.

And because they simply tinkered with a material already commonly used
for batteries, it could be easily adapted for commercial use.

"If manufacturers decide they want to go down this road, they could do
this in a few years," Ceder said.

One glitch, Ceder said, would be handling the extra surge of power. "All
of the wiring has to get beefed up," he said.

(Editing by Maggie Fox and Cynthia Osterman)
TTman - 12 Mar 2009 09:53 GMT
.SNIP

>to change," he said.
>
[quoted text clipped - 12 lines]
> One glitch, Ceder said, would be handling the extra surge of power. "All
> of the wiring has to get beefed up," he said.

Yes, and when it's built into a stack for a car, you will need 10,000 amps
to charge the car in 20 seconds.... and cables about 100mm diameter? How big
will the plug be?
The Natural Philosopher - 12 Mar 2009 15:46 GMT
> .SNIP
>
[quoted text clipped - 20 lines]
>
:-)

Not to mention what the actual weight and conversion efficiency of cells
capable of being slammed that hard is..

However three minute charge times would be similar to refuelling a gas
engine.

That might be a better and more practical target .

I saw my first Tesla yesterday. Bloody fast. Must have been doing about
80mph.

I guess it was on a test run as it was only 10 miles from the Lotus
factory...
ve7eje - 12 Mar 2009 17:17 GMT
> > .SNIP

Here is a bit more (and different) info.
http://www.theregister.co.uk/2009/03/12/fast_charge_battery_bubble_stab/
TTman - 13 Mar 2009 09:05 GMT
> .SNIP
>
[quoted text clipped - 18 lines]
> to charge the car in 20 seconds.... and cables about 100mm diameter? How
> big will the plug be?

On the other hand, in a cell phone I can see the advantage, along with all
other portable devices.
Glenn Møller-Holst - 12 Mar 2009 18:39 GMT
...
> However, about five years ago, Gerbrand Ceder and a team at MIT
> discovered that lithium ions in traditional lithium iron phosphate
> battery material actually move quite quickly.
...
> Using their new processing technique, the team made a small battery that
> could be fully charged in 10 to 20 seconds.
...

Hi!

They used a LiFePO4 based accumulator:

11 March 2009 Lithium batteries charge ahead.
Researchers demonstrate cells that can power up in seconds:
http://www.nature.com/news/2009/090311/full/news.2009.156.html?s=news_rss
Qoute: "...
That seemed to be the case for lithium iron phosphate (LiFePO4), a
material that is used in the cathode of a small number of commercial
batteries. But when Ceder and Kang did some calculations, they saw that
the compound could theoretically do much better. Its crystal structure
creates "perfectly sized tunnels for lithium to move through", says
Ceder. "We saw that we could reach ridiculously fast charging rates."
...
The authors helped the ions by coating the surface of the cathode with a
thin layer of lithium phosphate glass, which is known to be an excellent
lithium conductor. Testing their newly-coated cathode, they found that
they could charge and discharge it in as little as 9 seconds.
..."

Glenn
Doug McLaren - 12 Mar 2009 18:55 GMT
| Testing their newly-coated cathode, they found that
| they could charge and discharge it in as little as 9 seconds.

People thought 30C was a high discharge rate ...

Now we've got (do some math) 400C discharge (and charge) rates?

Whee!  Short circuits get even more exciting!

Signature

Doug McLaren, dougmc@frenzied.us
All that glitters has a high refractive index.

Glenn Møller-Holst - 12 Mar 2009 19:07 GMT
> | Testing their newly-coated cathode, they found that
> | they could charge and discharge it in as little as 9 seconds.
[quoted text clipped - 4 lines]
>
> Whee!  Short circuits get even more exciting!

or

fly/drive/sail some minutes...

charge 9 seconds...

fly/drive/sail some minutes...

...

Remember to reserve some charge to start car!

;-)

Glenn
Doug McLaren - 21 Mar 2009 05:04 GMT
...

| fly/drive/sail some minutes...
|
| charge 9 seconds...
|
| fly/drive/sail some minutes...

Well, even if 9s charge times aren't practical, batteries that can
tolerate a 400C rate will be able to handle a 20C discharge rate with
an almost zero voltage drop ...

It will be a good thing, even if you can't use it all.  And besides,
if you can't charge at 400C ... even 20C would be very nice -- fly
again in 3 minutes.

Signature

Doug McLaren, dougmc@frenzied.us
Television. Teacher, mother, secret lover. --Homer Simpson

Red Scholefield - 21 Mar 2009 19:41 GMT
Sorry ol buddy, but all of the parameters that facilitate faster charge
levels also deprecate
capacity and internal resistance.  Battery/cell design 101.  No free lunches
I'm afraid.
Signature

Red S.
Red's R/C Battery Clinic
http://www.rcbatteryclinic.com
Check us out for "revolting" information.

> ...
>
[quoted text clipped - 11 lines]
> if you can't charge at 400C ... even 20C would be very nice -- fly
> again in 3 minutes.
GerryGerry - 23 Mar 2009 12:33 GMT
I think Doug meant that as the batteries have the capability even though
charging them at their max rate was impractical there would be almost no
drop in use. I think this would be correct.

Gerry
> Sorry ol buddy, but all of the parameters that facilitate faster charge
> levels also deprecate
[quoted text clipped - 15 lines]
>> if you can't charge at 400C ... even 20C would be very nice -- fly
>> again in 3 minutes.
Doug McLaren - 23 Mar 2009 17:57 GMT
| I think Doug meant that as the batteries have the capability even though
| charging them at their max rate was impractical there would be almost no
| drop in use. I think this would be correct.

I imagine that Red understood me correctly.

However, any battery that can be charged (or discharged -- they said
that too) at 400C must have an extremely small internal resistance.

Yes, you generally do have a series of tradeoffs involved in designing
a battery -- you can maximize capacity at the expense of intenal
resistance, for example, and that's quite popular with consumer NiMH
AA cells.  And perhaps they have to give up a lot of capacity to get
something that can do 400C, but they still must be on to something.

But even if the 400C battery had half the capacity per weight/size of
a 30C cell it would still be very useful for certain applications.
R/C related, that would be great for a competition limited motor run
glider -- 30s of power, then the motor gets turns off.  So you put in
a battery only big enough to run the motor for say 60s, keeping weight
down.  Or in a hybrid car, you could have a tiny battery pack, perhaps
only big enough to run the motor for 60s -- enough to save the energy
from one braking and accelerate the car back up to speed again.

I always figured that it would be ultracapacitators that would fit
that niche first (they still need some work in the capacity arena
however) but maybe not.

|> Sorry ol buddy, but all of the parameters that facilitate faster charge
|> levels also deprecate
|> capacity and internal resistance.  Battery/cell design 101.  No free
|> lunches I'm afraid.

Signature

Doug McLaren, dougmc@frenzied.us
Our OS who art in CPU, UNIX be thy name.
       Thy programs run, thy syscalls done,
       In kernel as it is in user!

Tim Wescott - 23 Mar 2009 18:23 GMT
> | I think Doug meant that as the batteries have the capability even
> though | charging them at their max rate was impractical there would be
[quoted text clipped - 23 lines]
> niche first (they still need some work in the capacity arena however)
> but maybe not.

Or store the energy from one braking and then spin it out slowly to the
main pack.

Of course, "one braking" is different in Chicago than it is coming off
the summit of the Rockies.

Signature

http://www.wescottdesign.com

MJKolodziej - 23 Mar 2009 19:17 GMT
>> | I think Doug meant that as the batteries have the capability even
>> though | charging them at their max rate was impractical there would be
[quoted text clipped - 29 lines]
> Of course, "one braking" is different in Chicago than it is coming off
> the summit of the Rockies.

Interesting, could you re-charge your hybrid car on the way down IF you made
it to the summit?
mk
Tim Wescott - 23 Mar 2009 19:46 GMT
>>> | I think Doug meant that as the batteries have the capability even
>>> though | charging them at their max rate was impractical there would
[quoted text clipped - 36 lines]
> made it to the summit?
> mk

If it's a _Hybrid_ car you'd need to convert CO2 and water vapor back to
gasoline, which would be hard.

In theory, if it were all electric you should be able to recover a good
deal of the charge on the way down, but in practice you'd be limited both
by the battery's ability to absorb charge that quickly.  Even if you
could recover the power from the motor, that 'good deal of the charge' is
never going to be more than 50%, and will probably be more like 10-20.

Signature

http://www.wescottdesign.com

Glenn Møller-Holst - 24 Mar 2009 05:09 GMT
...
>> Interesting, could you re-charge your hybrid car on the way down IF you
>> made it to the summit?
[quoted text clipped - 8 lines]
> could recover the power from the motor, that 'good deal of the charge' is
> never going to be more than 50%, and will probably be more like 10-20.

Hi Tim and Doug

On the way down hill you simply charge stationary LiFePO4-accu via 9
seconds long eletrical road rails.

The energy can be stored, until another hybrid/electrical-vehicle needs
energy to climb the hill, which is supplied via 9 seconds long eletrical
rails on the other side of the road.

The eletrical rails could be near houses or pumped-storage hydroelectricity:
http://en.wikipedia.org/wiki/Pumped-storage_hydroelectricity

/Glenn
Glenn Møller-Holst - 24 Mar 2009 06:06 GMT
> ....
>>> Interesting, could you re-charge your hybrid car on the way down IF you
[quoted text clipped - 25 lines]
>
> /Glenn

Hi Tim and Doug

(follow-ups will default be sent to nntp://rec.models.rc.air )

If a electrical/hybrid vehicle can store 15kWh and weights 1000 kg and
is used on an earthly hill, it will ideally gain/loose the following
amount of electrical energy (using
http://en.wikipedia.org/wiki/Potential_energy ):

deltaE(J)=m*g*deltah <=> deltah = E(J)/(m*g)

deltaE(J) = 15kWh*3600J/Wh = 54MJ

e.g.

deltah = 54MJ/(1000kg*10m/s^2) = 5400 meters.

Which means that the vehicle in question, can ideally climb or descend
5,4km before (dis)charging. (unless I have made some sort of error)

-

Of course - the following will transform some of the gravitational
potential energy to heat, noise...:
*Wheel friction
*Wind turbulence
*Snow packing
*Mechanical friction
*Electrical losses in motor and ESC with regenerative braking

ESC:
http://en.wikipedia.org/wiki/Electronic_speed_control

A dream wheel?:

e-traction.com: TheWheel™ - what it is and what it does:
http://www.e-traction.com/TheWheel.htm
Quote: "...operating at more than 90% energy efficiency...delivers up to
120 KW of direct drive traction at the only place where it
matters,.....at the wheel...the braking action is converted back to
electrical power. This process is called regenerative braking..."

/Glenn
Doug McLaren - 26 Mar 2009 18:58 GMT
| If a electrical/hybrid vehicle can store 15kWh and weights 1000 kg and
| is used on an earthly hill, it will ideally gain/loose the following
| amount of electrical energy (using
...
| deltah = 54MJ/(1000kg*10m/s^2) = 5400 meters.

Your math is correct, though I just let google do the heavy lifting
for me --

  http://www.google.com/search?hl=en&q=15+kWh+%2F+g+%2F+1000+kg+in+meters
  (15 (kWh / g)) / (1000 kg) = 5506.46755 meters

However, 15 kWh is a big battery.  I think the energy density for good
LiPos is around 540 KJ/Kg?  That means your battery pack would weigh
around 100 Kg.  For the NiMH batteries used in current hybrids, their
energy density is about half that, so that's 200 Kg.

Also note that 1000 Kg is a small car -- even a Prius weighs more than
that, at around 1350 Kg, and that doesn't include fuel, cargo or
passengers.  And only about 45 Kg of that is battery.

Ultimately, I don't think that being able to store 15,000 feet worth
of descent in their batteries is really the intent of most hybrids.
Instead, they want to be able to store the energy produced by slowing
down from 70 mph or so a few times -- which works out to a gain of
only about 160 feet for each time.

http://www.google.com/search?hl=en&q=0.5+(70+mph)+^+2+%2F+g+in+feet

... but they have to keep a larger battery to keep the charge rate
down, and 400C batteries would let them use smaller batteries to keep
the weight and cost down.

Signature

Doug McLaren, dougmc@frenzied.us
`Sir, I protest! I am NOT a merry man!'  --Worf, ST:TNG

Wayne - 13 Mar 2009 05:06 GMT
> This is still in the works, but they say in 2 - 3 years we will be able
> to get them.
[quoted text clipped - 60 lines]
>
> (Editing by Maggie Fox and Cynthia Osterman)

http://www.pcworld.com/article/161116/article.html?tk=nl_dnxnws
Red Scholefield - 20 Mar 2009 18:24 GMT
Yippee! And we will have mini-fuel cells operating on cold fusion to charge
them. :-)

All in due time grasshopper.
Signature

Red S.
Red's R/C Battery Clinic
http://www.rcbatteryclinic.com
Check us out for "revolting" information.

> This is still in the works, but they say in 2 - 3 years we will be able to
> get them.
[quoted text clipped - 59 lines]
>
> (Editing by Maggie Fox and Cynthia Osterman)
 
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