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Model Forum / General / Rockets / January 2006



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Propellants on the explosives list

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David - 29 Dec 2005 18:35 GMT
It looks to me that Ammonium nitrate, potassium nitrate, and potassium
perchlorate composite propellants are not on the ATFE explosives list.  Only
APCP.  Is that correct?  What is the disadvantage of potassium perchlorate?
Lower ISP?

Thanks.

-- David
Binder Design - 30 Dec 2005 03:15 GMT
> What is the disadvantage of potassium perchlorate?>>>

High exponent.

Mike Fisher
David - 31 Dec 2005 00:41 GMT
Seems that it would have to be more than that.  A high exponent can be
managed with a reasonable chamber pressure by adjusting the Kn.  Would the
problem be that for commercial manufacturers, you can't ue the same nozzle
size for different burn rate catalysts because of the high exponent?

Thanks!

-- David

>> What is the disadvantage of potassium perchlorate?>>>
>
> High exponent.
>
> Mike Fisher
Binder Design - 31 Dec 2005 07:46 GMT
> Seems that it would have to be more than that.  A high exponent can be
> managed with a reasonable chamber pressure by adjusting the Kn.

I hear that the exponent is nearly unworkable.
Define "reasonable chamber pressure".  I know several people that have
tried to run Kp motors at low pressures.  At one nozzle throat size,
they would chuff.  At the next throat size down, they would cato.  I
hear that Kosdon has gotten them to work.  Feel free to let us know how
it turns out.

At any rate, just because they are not listed, it does not mean that
they escape the regulations of the ATF.  The orange book is written so
that it is basically all inclusive.  Basically if all of the propellant
manufacturers switched over to ANCP, the ATF would be just as vigilant
on regulating it as they have been on APCP.  Then we'd have a lower ISP
propellant, with the same regulations.  Not a good option IMO.

Mike Fisher
David - 01 Jan 2006 03:30 GMT
>> Seems that it would have to be more than that.  A high exponent can be
>> managed with a reasonable chamber pressure by adjusting the Kn.
[quoted text clipped - 5 lines]
> hear that Kosdon has gotten them to work.  Feel free to let us know how
> it turns out.

Ok, that makes sense.  Thanks for the info.

> At any rate, just because they are not listed, it does not mean that
> they escape the regulations of the ATF.  The orange book is written so
[quoted text clipped - 4 lines]
>
> Mike Fisher
Larry Curcio - 31 Dec 2005 12:43 GMT
Believe me, that's enough. Equilibrium chamber
pressure is proportional to

(BurningSurfaceArea/NozzleThroatArea)^(1/(1-n))

where n is the pressure exponent. With KN, chamber
pressure can increase with the fourth or fifth power of
burning surface area.

Also, the nozzle fouls and it blows up. The nozzle erodes
and it fizzles.

High exponents are bad news.

> Seems that it would have to be more than that.  A high exponent can be
> managed with a reasonable chamber pressure by adjusting the Kn.  Would the
[quoted text clipped - 10 lines]
> >
> > Mike Fisher
rocketdragon - 30 Dec 2005 03:37 GMT
Not one of them by itself is an explosive but that wouldn't stop them
from listing them. We are all going to be making our own engines soon
because BP is an explosive and that's what most of the hobby rockets
are.
raydunakin@aol.com - 30 Dec 2005 20:07 GMT
> Not one of them by itself is an explosive but that wouldn't stop them
> from listing them. We are all going to be making our own engines soon
> because BP is an explosive and that's what most of the hobby rockets
> are.

The ATF isn't going after modroc BP motors, just APCP motors.
Alan Jones - 31 Dec 2005 04:28 GMT
>> Not one of them by itself is an explosive but that wouldn't stop them
>> from listing them. We are all going to be making our own engines soon
>> because BP is an explosive and that's what most of the hobby rockets
>> are.
>
>The ATF isn't going after modroc BP motors, just APCP motors.

The ATF is not going after modroc APCP motors either.
David Schultz - 31 Dec 2005 14:38 GMT
> It looks to me that Ammonium nitrate, potassium nitrate, and potassium
> perchlorate composite propellants are not on the ATFE explosives list.  Only
[quoted text clipped - 4 lines]
>
> -- David

"While the list is
comprehensive, it is not all-inclusive.
The fact that an explosive material is
not on the list does not mean that it is
not within the coverage of the law if it
otherwise meets the statutory
definitions in 18 U.S.C. 841."

http://www.atf.gov/forms/notices/e5-7183.pdf

Signature

David W. Schultz
http://home.earthlink.net/~david.schultz/

"If we don't succeed, we run the risk of failure."
J, Danforth Quayle

Bob Kaplow - 31 Dec 2005 19:41 GMT
> "While the list is
> comprehensive, it is not all-inclusive.
[quoted text clipped - 3 lines]
> otherwise meets the statutory
> definitions in 18 U.S.C. 841."

Rocket propellant, be it APCP, KPCP, or whatever does not meet this
definition.

Thus the lawsuit...

Signature

 Bob Kaplow   NAR # 18L   >>> To reply, there's no internet on Mars (yet)! <<<
Kaplow Klips & Baffle:    http://nira-rocketry.org/Document/MayJun00.pdf
   www.encompasserve.org/~kaplow_r/    www.nira-rocketry.org    www.nar.org

       "To enslave men, successfully and safely, it is necessary to have
       their minds  occupied with thoughts and aspirations short of the
       liberty of which they are  deprived.  A certain degree of attainable
       good must be kept before them." Frederick Douglas, "My Bondage and
       My Freedom," 1855

 
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